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Kang Zhang Rong‐rong Wang Kai‐rui Zhang Fei Cheng Yu Tian Yi Lin Mi Zhou Pu‐xin Zhu 《Polymer International》2020,69(3):274-279
A series of hyperbranched poly(citric polyethylene glycol) (PCPEG) materials with varied polyethylene glycol (PEG) chain lengths as plasticizers were mixed with maize starch (MS) via cooking and film‐forming. The structure, pasting property, plasticization, aging property, moisture absorption and compatibility of plasticized starches were studied by means of Fourier transform infrared spectroscopy, X‐ray diffraction, rapid viscosity analysis, tension testing, moisture absorption measurements and scanning electron microscopy. Compared with PEG and citric acid, PCPEG was more effective in promoting starch chain movement and inhibiting the retrogradation of starch film. Also, PCPEG/MS had smaller moisture content. The longer the plasticizer chain, the better were the aging resistance and moisture resistance of starch. But with an increase of PEG chain length, mechanical properties of PCPEG/MS deteriorated and the compatibility between PCPEG and MS decreased. The hyperbranched derivative of PEG with longer chain exhibited improved plasticization and compatibility with starch. © 2019 Society of Chemical Industry 相似文献
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Chaoxin Li Yi Zhou Yuming Tian Yuanyuan Zhao Kaiyue Wang Guomin Li Yuesheng Chai 《Ceramics International》2019,45(5):5613-5616
Ceramics with mullite whiskers were prepared from coal fly ash and Al2O3 raw materials, with AlF3 used as an additive. The phase structures and microstructures of the ceramics were identified via X-ray diffraction and scanning electron microscopy, respectively. The results show that pickling of coal fly ash is an effective method for enhancing the flexural strength of ceramics. Sintering temperature and AlF3 addition were also key factors influencing the creation of ideal ceramics. The ceramic made from pickled coal fly ash, 6?wt% AlF3, and sintered at 1200?°C, exhibited the highest flexural strength of 59.1?MPa, and had a bulk density of 1.32?g/cm3 and porosity of 26.8%. The results show that ceramic materials made under these conditions are ideal candidates for manufacturing ceramic proppants for the exploitation of unconventional oil and gas resources. 相似文献
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Xiaohu Ren Xilou Pu Hongfeng Yin Yun Tang Hudie Yuan Huiqing Fan 《Ceramics International》2021,47(9):12122-12129
Hexagonal barium ferries is a promising and efficient microwave (MW) absorbing material, but the low dielectric loss and poor conductivity have limited their extensive applications. In this work, a simple tactic of coating conductive polymer PANI on hexaferrite BaCo2Fe16O27 is presented, wherein the dielectric properties are customized, and more significantly, the electromagnetic loss is greatly enhanced. As displayed from structural characterizations, PANI were coated equably on the surface of hexaferrite grains by an in-situ polymerization process. The outcomes exhibit the as-prepared PANI@hexaferrite composite has remarkable electromagnetic wave absorption capacity. When the thickness is 6.0 mm, the minimal RL of ?40.4 dB was achieved at 2.9 GHz. The effective absorption bandwidth (RL < ?20 dB) of 0.65 GHz, 0.53 GHz, 0.65 GHz, 0.52 GHz, 0.46 GHz and 0.39 GHz was achieved separately when the thickness ranges from 4 to 9 mm. The highly efficient MW absorbing performance of PANI@hexaferrite composite were the consequence of multiple loss mechanisms and perfect impedance matching. It is demonstrated that the PANI@hexaferrite composite with excellent MW absorption performance is expected to be potential MW absorbers for extensive applications. 相似文献
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进入新发展阶段,中国水资源安全保障需要以“节水优先、空间均衡、系统治理、两手发力”治水思路为指导,厘清问题、研判趋势、优化对策,支撑新阶段水利高质量发展。本文在全面分析我国水资源安全保障存在的突出问题与面临形势基础上,阐述了新发展阶段中国水资源安全保障的基本思路与战略路径,从保证资源安全、构建国家水网、强化供水保障、建设美丽河湖、改善水环境质量等方面提出了战略对策和需要进一步回答的重大问题,以期为完善新发展阶段中国水资源安全保障战略,全面提高国家水资源安全保障能力提供有力支撑。 相似文献
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随着科学技术水平的不断提高,在学校教育中应用多媒体CAI的现象越来越普遍,并且受到了广大师生的喜爱。在篮球技术教学中,多媒体CAI课件得到了广泛的应用,并且发挥了非常重要的作用,促进了学生篮球技术水平的提高,实现了预期的教学效果。 相似文献
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为了揭示吐哈盆地克尔碱凹陷不同矿区煤质形成条件,探讨该区煤质与成煤环境的关系,基于对主采煤层样品工业分析、有害组分及灰成分指标等数据分析,在对克尔碱凹陷地层分布、含煤岩系特征等基本地质条件分析的基础上,运用煤地质学、煤岩学、煤化学等理论和方法,系统总结凹陷内各矿区煤层赋存特征、煤质特征,探讨区内煤岩煤质与成煤环境的关系。结果表明:研究区自西向东划分6个主要矿区,区内煤层主要发育于中侏罗统西山窑组(J2x)和下侏罗统八道湾组(J1b)地层之中。研究区煤质呈低灰、低硫、高挥发分特征,煤灰成分以SiO2、Al2O3为主。综合分析表明,研究区中-下侏罗统主要煤层形成于湖泊-河流三角洲淡水沉积环境,具陆相成煤特征,成煤环境温暖潮湿。 相似文献
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